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Product Details:
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Purity: | 99%min | Application: | Pharmaceutical Intermediates |
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Type: | Pharmaceutical | Appearance: | Transparent Liquid |
Product Name: | BDO | Packing: | Customers' Requirement |
Cas: | 110-63-4 | Shelf Life: | 2 Years |
Whatsapp: | 008615512123605 | Moq: | 1kg |
Delivery Time: | After Payment In 3 Days Send Out | Package: | Aluminium Foil Bag |
High Light: | 99%Min Chemicals Intermediates Colorless Liquid,Liquid BDO C4H10O2 CAS 110-63-4 |
Product Name: |
BDO
|
Product Name: | 110-63-4 |
Synonyms: | 1,4-BUTYLENE GLYCOL;1,4-BUTANEDIOL;1,4-DIHYDROXYBUTANE;AKOS BBS-00004303;BDO;BUTANEDIOL, 1,4-;TETRAMETHYLENE GLYCOL;VERSALINK CURATIVE 1,4 BDO |
CAS: | 110-63-4 |
MF: | C4H10O2 |
MW: | 90.12 |
EINECS: | 203-786-5 |
Mol File: | 110-63-4 |
specification
Melting point | 16 °C (lit.) |
Boiling point | 230 °C (lit.) |
density | 1.017 g/mL at 25 °C (lit.) |
vapor density | 3.1 (vs air) |
vapor pressure | <0.1 hPa (20 °C) |
refractive index | n20/D 1.445(lit.) |
Fp | 135 °C |
storage temp. | Store below +30°C. |
form | Liquid |
pka | 14.73±0.10(Predicted) |
color | Clear colorless |
Odor | Odorless |
PH | 7-8 (500g/l, H2O, 20℃) |
explosive limit | 1.95-18.3%(V) |
Water Solubility | Miscible |
Sensitive | Hygroscopic |
BRN | 1633445 |
Stability: | Stable. Combustible. Incompatible with strong oxidizing agents, mineral acids, acid chlorides, acid anhydrides. |
InChIKey | WERYXYBDKMZEQL-UHFFFAOYSA-N |
NIST Chemistry Reference | 1,4-Butanediol(110-63-4) |
EPA Substance Registry System | 1,4-Butanediol (110-63-4) |
Chemical Properties
Chemical Properties | 1,4-butanediol (1,4-BD) is a colorless, viscous liquid derived from butane by placement of alcohol groups at each end of its molecular chain and is one of four stable isomers of butanediol.the hydroxyl function of each end group of the Butanediol reacts with different mono- and bifunctional reagents: for example with dicarboxylic acids to polyesters, with diisocyanates to polyurethanes, or with phosgene to polycarbonates. 1.4-Butanediol (BDO) is a high-quality intermediate. BDO and its derivatives are widely used for producing plastics, solvents, electronic chemicals and elastic fibers. Additionally BDO is also a building block for the synthesis of polyesterpolyols and polyetherpolyols. BASF is the most significant producer of 1,4-Butanediol and its derivatives worldwide. |
Uses |
|
Uses | butylene glycol is a solvent with good antimicrobial action. It enhances the preservative activity of parabens. Butylene glycol also serves as a humectant and viscosity controller, and to mask odor. |
Uses | 1,4-Butanediol is used to produce polybutyleneterephthalate, a thermoplastic polyester;and in making tetrahydrofuran, butyrolactones,and polymeric plasticizers. |
Production Methods | Methods of manufacturing: The most prevalent 1,4-BD production route worldwide is BASF's Reppe process, which reacts acetylene and formaldehyde. Acetylene reacts with two equivalents of formaldehyde to form 1,4-butynediol, also known as but-2-yne- 1,4-diol. Hydrogenation of 1,4-butynediol gives 1,4-butanediol. 1,4-BD is also made on a large industrial scale by continuous hydrogenation of the 2-butyne- 1,4-diol over modified nickel catalysts. The one-stage flow process is carried out at 80 - 160 deg C and 300 bar. Mitsubishi uses a three-step process: (1) the catalytic reaction of butadiene and acetic acid yields 1,4-diacetoxy-2-butene; (2) subsequent hydrogenation gives 1,4-diacetoxybutane; and (3) hydrolysis leads to 1,4-butanediol. |
Synthesis Reference(s) | The Journal of Organic Chemistry, 36, p. 2018, 1971 DOI: |
General Description | Odorless colorless liquid or solid (depending upon temperature). |
Air & Water Reactions | Highly flammable. 1,4-Butanediol is hygroscopic. Water soluble. |
Reactivity Profile | 1,4-Butanediol is heat and light sensitive. 1,4-Butanediol reacts with acid chlorides, acid anhydrides and chloroformates; reacts with oxidizing agents and reducing agents. 1,4-Butanediol is incompatible with isocyanates and acids; also incompatible with peroxides, perchloric acid, sulfuric acid, hypochlorous acid, nitric acid, caustics, acetaldehyde, nitrogen peroxide and chlorine. |
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1,4-Butanediol cas 110-63-4 99.9% colorless liquid cas 110-63-4
Product Detail of BDO:
1,4-Butanediol (BDO) is a non-corrosive, colorless, high boiling liquid with a low order of toxicity.BDO is completely soluble in water, most alcohols, esters, ketones, glycol ethers and acetates,but may be immiscible or partially miscible in common aliphatic and aromatic/chlorinated hydrocarbons. BDO is produced by Lyondell Chemical Company in a proprietary, multi-step reaction from propylene oxide. BDO is a versatile chemical intermediate because of its terminal, primary hydroxyl groups and its hydrophobic and chemical resistant nature. Polymers produced upon reaction with diacids
Properties Of 1,4- Butanediol:
Melting point :16 °C (lit.)
Boiling point :230 °C (lit.)
Density :1.017 g/mL at 25 °C (lit.)
vapor density :3.1 (vs air)
vapor pressure :<0.1 hPa (20 °C)
refractive index :n 20/D 1.445(lit.)
Flash point :135 °C
storage temp. :Store below +30°C.
form :Liquid
pka :14.73±0.10(Predicted)
color :Clear colorless
Odor :Odorless
PH :7-8 (500g/l, H2O, 20℃)
explosive limit :1.95-18.3%(V)
Water Solubility :Miscible
Sensitive :Hygroscopic
Stability :Stable. Combustible. Incompatible with strong oxidizing agents, mineral acids, acid chlorides, acid anhydrides.
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